Nacreous colorant for keratin fibers

ABSTRACT

The dye carrier composition containing oxidative and/or nonoxidative dyes has a nacreous luster because it contains a combination of
     (a) 6.1 to 20 weight percent of at least one fatty alcohol with 14 to 20 carbon atoms,   (b) 6.1 to 20 weight percent of at least one alkanolamide,   (c) 0.1 to 15 weight percent of at least one fatty alcohol alkoxylate or fatty acid alkoxylate and   (d) 0.1 to 15 weight percent of at least one anionic surfactant,
       wherein the weight ratio of fatty alcohol (a) to alkanolamide (b) is equal to 0.5:2 to 2:0.5, preferably from 0.8:1.2 to 1.2:0.8. The weight ratio of alkoxylate to anionic surfactant is preferably from 0.5:2 to 2:0.5.

CROSS-REFERENCE

This is the US National Stage of PCT/EP 2004/011790, filed on Oct. 19,2004 in Europe, which discloses the same invention as DE 10 2004005768.0, filed Feb. 5, 2004 in Germany. The aforesaid German PatentApplication provides the basis for a claim of priority for the inventiondescribed and claimed herein below under 35 U.S.C. 365 (b) and 35 U.S.C.119 (a) to (d).

BACKGROUND OF THE INVENTION

The invention has for an object agents with a nacreous luster forcoloring keratin fibers, particularly human hair, containing directand/or oxidative dyes and a special combination of fatty alcohols,alkanolamides, alkoxylates and anionic surfactants, and the use of theaforesaid combination for producing a stable nacreous luster in haircolorants.

Coloring preparations are usually in the form of aqueous—preferablythickened—solutions or emulsions and besides dyes contain, for example,fatty alcohols and/or other oil components, emulsifiers, surfactants andoptionally alcohols. Oxidation dyes as a rule consist of two components:(i) the dye carrier composition containing the dyes and (ii) the oxidantpreparation, which are mixed with one another just before use and arethen applied to the hair to be colored. If the coloring preparations arein the form of an emulsion, they are as a rule creams, but to obtain anacreous luster effect it is necessary to add to them a special nacreousluster-imparting additive.

From DE-A 38 34 142 are known creamy hair colorants containing amultiplicity of raw materials including fatty alcohols and fattyalkanolamides as well as anionic and nonionic surfactants. Thesecolorants, however, do not have a nacreous luster.

SUMMARY OF THE INVENTION

The purpose was therefore to develop a coloring composition whichwithout the addition of a nacreous luster-imparting agent would by theselection of the raw materials alone have a stable nacreous characterthat would be retained even after the mixing with the oxidantpreparation. Moreover, the hair-care effect after rinsing out the dyecomposition was to be improved over that of prior-art formulations.

We have now found that this objective can be reached in outstandingfashion by way of a combination of a fatty alcohol, alkanolamide,alkoxylate and anionic surfactant.

The object of the present invention is therefore a dye carriercomposition containing oxidative and/or non-oxidative (“direct”) dyes,characterized in that it contains a combination of

-   (a) 6.1 to 20 weight percent of at least one fatty alcohol with 14    to 20 carbon atoms,-   (b) 6.1 to 20 weight percent of at least one alkanolamide,-   (c) 0.1 to 15 weight percent of at least one fatty alcohol    alkoxylate or fatty acid alkoxylate and-   (d) 0.1 to 15 weight percent of at least one anionic surfactant,    the weight ratio of fatty alcohol (a) to fatty alkanolamide (b)    being 0.5:2 to 2:0.5.

DESCRIPTION OF THE PREFERRED EMBODIMENTS

Particularly preferred are dye carrier compositions wherein the fattyalcohol (a) and the alkanolamide (b) are present in a weight ratio from0.8:1.2 to 1.2:0.8.

In addition, to obtain a particularly beautiful nacreous character andan unusually high hair-care effect after rinsing out the dye carrier, itis advantageous if the weight ratio of alkoxylate (c) to anionicsurfactant (d) is equal to 0.5:2 to 2:0.5, a (c) to (d) weight ratio of0.8:1.2 to 1.2:0.8 being particularly preferred.

Long-chain fatty alcohols with 14 to 20 carbon atoms suitable accordingto the invention are, for example, cetyl alcohol, stearyl alcohol,myristyl alcohol, isooctyl alcohol or isotridecyl alcohol. In the dyecarrier composition of the invention, the fatty alcohols can be usedalone or in combination with one another.

Alkanolamides suitable according to the invention are, in particular,the N-acyl derivatives of monoethanolamine or diethanolamine, forexample the monoethanolamides or diethanolamides, or ester amides, suchas coco fatty acid monoethanolamide.

Alkoxylates (c) suitable according to the invention are in particularethoxylated fatty alcohols or fatty alcohol polyglycol ethers of thefollowing formula:CH₃(CH₂)x-O—(Ry)-H  (I)[wherein R=(CH₂—CH₂—O) or (CH₃—CH—CH₂—O); x=C₈-C₁₈ and y=2 to 300]

Particularly preferred fatty alcohol alkoxylates are, for example, thepolyethylene glycol ethers of stearyl alcohol, for example Steareth-10,Ceteareth-25 or Steareth-20.

According to the invention, suitable anionic surfactants are the saltsand esters of carboxylic acids, alkyl ether sulfates and alkyl sulfates,fatty alcohol ether sulfates, sulfonic acids and salts thereof(sulfosuccinates, fatty acid isethionates etc), phosphate esters andsalts thereof and acylamino acids and salts thereof.

A detailed description of these anionic surfactants can be found in thepublication “FIEDLER—Lexikon der Hilfsfoffe” [FIEDLER—Encyclopedia ofAuxiliary Substances], vol. 1, 5th edition (2002), pages 97 to 102, towhich we hereby specifically refer.

The fatty alcohol of component (a) and the alkanolamide of component (b)are used in the dye carrier composition of the invention in a totalamount from 7 to 12 weight percent each.

The alkoxylate of component (c) and the anionic surfactant of component(d) are preferably used in the dye carrier composition of the inventionin a total amount from 7 to 12 weight percent each.

The dye carrier composition of the invention is preferably free ofmonomeric quaternary ammonium compounds and cationic emulsifiers andsurfactants and optionally contains from 0.1 to 10 weight percent andpreferably from 0.5 to 4 weight percent of ethylene glycol distearate.

The dye carrier composition of the invention preferably containsoxidation dye precursors from which the color is produced by action ofan oxidant, for example hydrogen peroxide or an adduct thereof, or inthe presence of atmospheric oxygen.

Suitable oxidation dye precursors are, for example the followingdevelopers and couplers and self-coupling compounds:

-   (i) Developers: 1,4-diaminobenzene (p-phenylenediamine),    1,4-diamino-2-methylbenzene (p-touylenediamine),    1,4-diamino-2,6-dimethylbenzene,1,4-diamino-3,5-diethylbenzene,1,4-diamino-mino-2,5-dimethylbenzene,    1,4-diamino-2,3-dimethylbenzene, 2-chloro-1,4-diaminobenzene,    1,4-diamino-2-(thiophen-2-yl)benzene,    1,4-diamino-2-(thiophen-3-yl)benzene,    1,4-diamino-2-(pyridin-3-yl)-benzene, 2,5-diaminobiphenyl,    1,4-diamino-2-methoxymethylbenzene,    1,4-diamino-2-amino-methylbenzene,    1,4-diamino-2-hydroxymethylbenzene,    1,4-diamino-2-(2-hydroxyethoxy)benzene,    2-[(2-acetylamino)ethoxy]-1,4-diaminobenzene, 4-phenylaminoaniline,    4-dimethylaminoaniline, 4-diethylaminoaniline,    4-dipropylaminoaniline, 4-[ethyl(2-hydroxyethyl)amino]aniline,    4-[di(2-hydroxy-ethyl)amino]aniline,    4-[di(2-hydroxyethyl)amino-2-methylaniline,    4-[(2-methoxyethyl)amino]aniline, 4-[(3-hydroxypropyl)amino]aniline,    4-[(2,3-dihydroxypropyl)amino]aniline,    1,4-diamino-2-(2-hydroxyethyl)benzene,    1,4-diamino-2-(1-methylethyl)benzene,    1,3-bis[(4-aminophenyl)(2-hydroxyethyl)-amino]-2-propanol,    1,4-bis[(4-aminophenyl)amino]butane,    1,8-bis(2,5-diaminophenoxy)-3,6-dioxaoctane, 4-aminophenol,    4-amino-3-methylphenol, 4-amino-3-(hydroxymethyl)phenol,    4-amino-3-fluorophenol, 4-methylaminophenol,    4-amino-2-(aminomethyl)phenol, 4-amino-2-(hydroxymethyl)-phenol,    4-amino-2-fluorophenol,    4-amino-2-[(2-hydroxyethyl)amino]methylphenol,    4-amino-2-methylphenol, 4-amino-2-(methoxymethyl)phenol,    4amino-2-(2-hydroxyethyl)phenol, 5-aminosalicylic acid,    2,5-diaminopyridine, 2,4,5,6-tetraaminopyrimidine,    2,5,6-triamino-4-(1H)-pyrimidone,    4,5-diamino-1-(2-hydroxyethyl)-1H-pyrazole,    4,5-diamino-1-(1-methylethyl)-1H-pyrazole,    4,5-diamino-1-[(4-methylphenyl)methyl]-1H-pyrazole,    1-[(4-chlorophenyl)methyl]-4,5-diamino-1H-pyrazole,    4,5-diamino-1-methyl-1H-pyrazole, 2-aminophenol,    2-amino-6-methylphenol and 2-amino-5-meth-ylphenol, alone or in    admixture with one another.-   (ii) Couplers: N-(3-Dimethylaminophenyl)urea, 2,6-diaminopyridine,    2-amino-4-[(2-hydroxyethyl)amino]anisole,    2,4-diamino-1-fluoro-5-methylbenzene,    2,4amino-1-methoxy-5-methylbenzene,    2,4-diamino-1-ethoxy-5-methylbenzene,    2,4diamino-1-(2-hydroxyethoxy)-5-methylbenzene,    2,4-di[(2-hydroxyethyl)amino]-1,5-dimethoxybenzene,    2,3-diamino-6-methoxypyridine,    3-amino-6-methoxy-2-(methylamino)pyridine,    2,6-diamino-3,5-dimethoxypyridine,    3,5-diamino-2,6-dimethoxy-pyridine, 1,3-diaminobenzene,    2,4-diamino-1-(2-hydroxyethoxy)benzene,    1,3-diamino-4-(2,3-dihy-droxypropoxy)benzene,    2,4-diamino-1,5-di(2-hydroxyethoxy)benzene,    1-(2-aminoethoxy)-2,4-di-aminobenzene,    2-amino-1-(2-hydroxyethoxy)-4-methylaminobenzene,    2,4-diaminophenoxyacetic acid, 3-[di(2-hydroxyethyl)amino]aniline,    4-amino-2-di[(2-hydroxyethyl)amino]-1-ethoxybenzene,    5-methyl-2-(1-methylethyl)phenol, 3-[(2-hydroxyethyl)amino]aniline,    3-[(2-aminoethyl)amino]aniline, 1,3-di(2,4-diaminophenoxy)propane,    di(2,4-diaminophenoxy)methane, 1,3-diamino-2,4-dimethoxy-benzene,    2,6-bis(2-hydroxyethyl)aminotoluene, 4-hydroxyindole,    3-dimethylaminophenol, 3-dieth-ylaminophenol,    5-amino-2-methylphenol, 5-amino-4-fluoro-2-methylphenol,    5-amino-4-methoxy-2-methylphenol, 5-amino-4-ethoxy-2-methylphenol,    3-amino-2,4-dichlorophenol, 5-amino-2,4-dichlo-rophenol,    3-amino-2-methylphenol, 3-amino-2-chloro-6-methylphenol,    3-aminophenol, 2-[(3-hydroxyphenyl)amino]acetamide,    5-[(2-hydroxyethyl)amino]-4-methoxy-2-methylphenol,    5-[(2-hydroxyethyl)amino]-2-methylphenol,    3[(2-hydroxyethyl)amino]phenol, 3-[(2-methoxyethyl)amino]phenol,    5-amino-2-ethylphenol, 5-amino-2-methoxyphenol,    2-(4-amino-2-hydroxyphenoxy)ethanol,    5-[(3-hydroxypropyl)amino]-2-methylphenol,    3-[(2,3-dihydroxypropyl)amino]-2-methylphenol,    3-[(2-hydroxyethyl)amino]-2-methylphenol, 2-amino-3-hydroxypyridine,    5-amino-4-chloro-2-methylphenol, 1-naphthol, 2-methyl-1-naphthol,    1,5-dihydroxynaphthalene, 1,7-dihydroxynaphthalene,    2,3-dihydroxynaphthalene, 2,7-dihydroxynaphthalene,    2-methyl-1-naphthol acetate, 1,3-dihydroxybenzene,    1-chloro-2,4-dihydroxybenzene, 2-chloro-1,3-dihydroxybenzene,    1,2-dichloro-3,5-dihydroxy-4-methylbenzene,    1,5-dichloro-2,4-dihydroxybenzene, 1,3-dihydroxy-2-methylbenzene,    3,4-methylenedioxyphenol, 3,4-methylenedioxyaniline,    5-[(2-hydroxyethyl)amino]-1,3-benzodioxol,    6-bromo-1-hydroxy-3,4-methylenedioxybenzene, 3,4-diaminobenzoic    acid, 3,4-dihydro-6-hydroxy-1,4(2H)-benzoxazine,    6-amino-3,4-dihydro-1,4(2H)-benzoxazine,    3-methyl-1-phenyl-5-pyrazolone, 5,6-dihydroxyindole,    5,6-dihydroxyindoline, 5-hydroxyindole, 6-hydroxyindole,    7-hydroxyindole and 2,3-indolinedione, alone or in admixture with    one another.-   (iii) Self-coupling compounds: 2-amino-5-methylphenol,    2-amino-6-methylphenol, 2-amino-5-ethoxyphenol or    2-propylamino-5-aminopyridine.

The total amount of oxidation precursors contained in the dye carriercomposition of the invention is about 0.01 to 12 weight percent andparticularly about 0.2 to 6 weight percent.

Moreover, to achieve certain color nuances the colorant can also containcommon natural and/or synthetic direct dyes, for example vegetable dyessuch as henna or indigo, triphenylmethane dyes, aromatic nitro dyes, azodyes, quinone dyes or cationic or anionic dyes.

Suitable synthetic dyes are for example, the following:1,4-bis[(2-hydroxyethyl)amino]-2-nitrobenzene,1-(2-hydroxyethyl)amino-2-nitro-4-[di(2-hydroxyethyl)amino]benzene (HCBlue No. 2), 1-amino-3-methyl-4-[(2-hydroxyethyl)amino]-6-nitrobenzene(HC Violet No. 1),4-[ethyl-(2-hydroxyethyl)amino]-1-[(2-hydroxyethyl)amino]-2-nitrobenzenehydrochloride (HC Blue No. 12),4-[di(2-hydroxyethyl)amino]-1-[(2-methoxyethyl)amino]-2-nitrobenzene (HCBlue No. 11),1-[(2,3-di-hydroxypropyl)amino]-4[methyl-(2-hydroxyethyl)amino]-2-nitrobenzene(HC Blue No. 10),1-[(2,3-dihydroxypropyl)amino]-4-[ethyl-(2-hydroxyethyl)amino]-2-nitrobenzenehydrochloride (HC Blue No. 9),1-(3-hydroxypropylamino)-4-[di(2-hydroxyethyl)amino]-2-nitrobenzene (HCViolet No. 2),1-methylamino-4-[methyl-(2,3-dihydroxypropyl)amino]-2-nitrobenzene (HCBlue No. 6), 2-[(4-amino-2-nitrophenyl)amino]-5-dimethylaminobenzoicacid (HC Blue No. 13), 1-amino-4-[(2-hydroxyethyl)amino]-2-nitrobenzene(HC Red No. 7), 2-amino-4,6-dinitrophenol, 4-amino-2-nitrodiphenylamine(HC Red No. 1), 1-amino-4-[di(2-hydroxyethyl)amino]-2-nitrobenzenehydrochloride (HC Red No. 13),1-amino-5-chloro-4-[(2-hydroxyethyl)amino]-2-nitrobenzene,4-amino-1-[(2-hydroxyethyl)amino]-2-nitrobenzene (HC Red No. 3),4-amino-3-nitrophenol, 4-[(2-hydroxyethyl)-amino]-3-nitrophenol,1-[(2-aminoethyl)amino]-4-(2-hydroxyethoxy)-2-nitrobenzene (HC OrangeNo. 2),4-(2,3-dihydroxypropoxy)-1-[(2-hydroxyethyl)amino]-2-nitrobenzene (HCOrange No. 3),1-amino-5-chloro-4-[(2,3-dihydroxypropyl)amino]-2-nitrobenzene (HC RedNo. 10), 5-chloro-1,4-[di(2,3-dihydroxypropyl)amino]-2-nitrobenzene (HCRed No. 11), 2-[(2-hydroxyethyl)amino]-4,6-dinitrophenol,4-ethylamino-3-nitrobenzoic acid,2-[(4-amino-2-nitrophenyl)amino]benzoic acid,2-chloro-6-ethylamino-4-nitrophenol, 2-amino-6-chloro-4-nitrophenol,4-[(3-hydroxypropyl)amino]-3-nitrophenol, 2,5-diamino-6-nitropyridine,1,2,3,4-tetrahydro-6-nitroquinoxaline,7-amino-3,4-dihydro-6-nitro-2H-1,4-benzoxazine, (HC Red. No. 14),1-amino-2-[(2-hydroxy-ethyl)amino]-5-nitrobenzene (HC Yellow No. 5),1-(2-hydroxyethoxy)-2-[(2-hydroxyethyl)amino]-5-nitrobenzene (HC YellowNo. 4), 1-[(2-hydroxyethyl)amino]-2-nitrobenzene (HC Yellow No. 2),2-[(2-hydroxyethyl)amino]-1-methoxy-5-nitrobenzene,2-amino-3-nitrophenol, 1-(2-hydroxyethoxy)-3-methylamino-4-nitrobenzene,2,3-(dihydroxypropoxy)-3-methylamino-4-nitrobenzene,2-[(2-hydroxyethyl)-amino]-5-nitrophenol (HC Yellow No. 11),3-[(2-aminoethyl)amino]-1-methoxy-4-nitro-benzene hydrochloride (HCYellow No. 9), 1-[(2-ureidoethyl)amino]-4-nitrobenzene,4-[(2,3-dihydroxypropyl)amino]-3-nitro-1-trifluoromethylbenzene (HCYellow No. 6), 1-chloro-2,4-bis[(2-hydroxyethyl)amino]-5-nitrobenzene(HC Yellow No. 10), 4[(2-hydroxyethyl)amino]-3-nitro-1-methylbenzene,1-chloro-4-[(2-hydroxyethyl)amino]-3-nitrobenzene (HC Yellow No. 12),4-[(2-hydroxyethyl)amino]-3-nitro-1-trifluoromethylbenzene (HC YellowNo. 13), 4-[(2-hydroxyethyl)amino]-3-nitrobenzonitrile (HC Yellow No.14), 4-[(2-hydroxyethyl)amino]-3-nitrobenzamide (HC Yellow No. 15),1,4-di[(2,3-dihydroxypropyl)amino]-9,10-anthraquinone,1-[(2-hydroxyethyl)amino]-4-methylamino-9,10-anthraquinone (CI 61505,Disperse Blue No. 3), 2-[(2-aminoethyl)amino]-9,10-anthraquinone (HCOrange No. 5),1-hydroxy-4-[(4-methyl-2-sulfophenyl)amino]-9,10-anthraquinone,1-[(3-aminopropyl)amino]-4-methylamino-9,10-anthraquinone (HC Blue No.8), 1-[(3-aminopropyl)-amino]-9, 10-anthraquinone (HC Red No. 8),1,4-diamino-2-methoxy-9, 1 0-anthraquinone (CI 62015, Disperse Red No.11, Solvent Violet No. 26),1,4-dihydroxy-5,8-bis[2-hydroxyethyl)amino]-9,10-anthraquinone (CI62500, Disperse Blue No. 7, Solvent Blue No. 69),9-(dimethylamino)-benzo[a]-phenoxazin-7-ium chloride (CI 51175; BasicBlue No. 6), di[4-(diethylamino)phenyl][4-(ethylamino)naphthyl]carbeniumchloride (CI 42595; Basic Blue No. 7),3,7-di(dimethyl-amino)phenothiazin-5-ium chloride (CI 52015; Basic BlueNo. 9), di[4-(dimethylamino)phenyl][4-(phenylamino)naphthyl]carbeniumchloride (CI 44045; Basic Blue No. 26),2-{[4-(ethyl(2-hydro-xyethyl)amino)phenyl]azo}-6-methoxy-3-methylbenzothiazoliummethylsulfate (CI 11154; Basic Blue No. 41),8-amino-2-bromo-5-hydroxy-4-imino-6-{[3-(trimethylammonio)phenyl]amino}-1(4H-naphthalenonechloride (CI 56059; Basic Blue No. 99),bis[4-(dimethyl-amino)phenyl][4-(methylamino)phenyl]carbenium chloride(CI 42535; Basic Violet No. 1), tris[4-(dimethyl-amino)phenyl]carbeniumchloride (CI 42555; Basic Violet No. 3),2-[3,6-(diethylamino)-dibenzopyranium-9-yl]benzoyl chloride (CI 45170;Basic Violet No. 10), di(4-aminophenyl)(4-amino-3-methylphenyl)carbeniumchloride (CI 42510, Basic Violet No. 14),1,3-bis[(2,4-dia-mino-5-methylphenyl)azo]-3-methylbenzene (CI 21010;Basic Brown No. 4),1-[(4-aminophenyl)azo]-7-(trimethylammonio)-2-naphthol chloride (CI12250; Basic Brown No. 16),1-[(4-amino-2-nitrophenyl)azo]-7-(trimethylammonio-2-naphthol chloride(Basic Brown No. 17),1-[(4-amino-3-nitrophenyl)azo]-7-(trimethylammonio)-2-naphthol chloride(CI 12251; Basic Brown No. 17 [sic]),3,7-diamino-2,8-dimethyl-5-phenylphenazinium chloride (CI 50240; BasicRed No. 2),1,4-dimethyl-5-{[(4-(dimethylamino)phenyl]azo}-1,2,4-triazolium chloride(CI 11055; Basic Red No. 22),2-hydroxy-1-[(2-methoxyphenyl)azo]-7-(trimethylammonio)naphthalenechloride (CI 12245; Basic Red No. 76),2-{2-[(2,4-dimethoxyphenyl)amino]ethenyl}-1,3,3-trimethyl-3H-indol-1-iumchloride (CI 48055; Basic Yellow No. 11),3-methyl-1-phenyl-4-{[3-(trimethylammonio)phenyl]azo}pyrazol-5-onechloride (CI 12719; Basic Yellow No. 57),bis[4-(diethylamino)phenyl]phenylcarbenium hydrogen sulfate (1:1) (CI42040; Basic Green No. 1),1-[di(2-hydroxyethyl)amino]-3-methyl-4-[(4-nitrophenyl)azo]benzene (CI11210; Disperse Red No. 17),4-[(4-aminophenyl)azo]-1-[di(2-hydroxyethyl)amino]-3-methylbenzene (HCYellow No. 7), 2,6-diamino-3-[(pyridin-3-yl)-azo]pyridine,6-hydroxy-5-[(4-sulfophenyl)azo]-2-naphthalenesulfonic acid disodiumsalt (CI 15985; Food Yellow No. 3; FD&C Yellow No. 6),2,4-dinitro-1-naphthol-7-sulfonic acid disodium salt (CI 10316; AcidYellow No. 1; Food Yellow No. 1),2-(indan-1,3-dion-2-yl)-quinoline-x,x-sulfonic acid (mixture of mono-and disulfonic acid) (CI 47005; D&C Yellow No. 10; Food Yellow No. 13;Acid Yellow No. 3),5-hydroxy-1-(4-sulfophenyl)-4-[(4-sulfophenyl)azo]pyrazole-3-carboxylicacid trisodium salt (CI 19140; Food Yellow No. 4; Acid Yellow No. 23),9-(2-carboxyphenyl)-6-hydroxy-3H-xanthen-3-one (CI 45350; Acid YellowNo. 73; D&C Yellow No. 8),5-[(2,4-dinit-rophenyl)amino]-2-phenylaminobenzenesulfonic acid sodiumsalt (CI 10385; Acid Orange No. 3),4-[(2,4-dihydroxyphenyl)azo]benzenesulfonic acid monosodium salt (CI14270; Acid Orange No. 6), 4-[(2-hydroxynaphth-1-yl)azo]benzenesulfonicacid sodium salt (CI 15510; Acid Orange No. 7),4-[(2,4-dihydroxy-3-[(2,4-dimethylphenyl)azo]phenyl)azo]benzenesulfonicacid sodium salt (CI 20170; Acid Orange No. 24),4-hydroxy-3-[(4-sulfonaphth-1-yl)azo]-1-naphthalenesulfonic aciddisodium salt (CI 14720; Acid Red No. 14),6-hydroxy-5-[(4-sulfonaphth-1-yl)azo]-2,4-naphthalenedisulfonic acidtrisodium salt (CI 16255; Ponceau 4R; Acid Red No. 18),3-hydroxy-4-[(4-sulfonaphth-1-yl)azo]-2,7-naphthalenedisulfonic acidtrisodium salt (CI 16185; Acid Red No. 27),8-amino-1-hydroxy-2-(phenylazo)-3,6-naphthalenedisulfonic acid disodiumsalt (CI 17200; Acid Red No. 33),5-(acetylamino)-4-hydroxy-3-[(2-methylphenyl)azo]-2,7-naphthalenedisulfonicacid disodium salt (CI 18065; Acid Red No. 35),2-(3-hydroxy-2,4,5,7-tetraiododibenzopyran-6-n-9-yl)benzoic aciddisodium salt (CI 45430; Acid Red No. 51),N-[6-(diethylamino)-9-(2,4-disulfophenyl)-3H-xanthen-3-ylidene]-N-ethylethanammoniumhydroxide, inner salt, sodium salt (CI 45100; Acid Red No. 52),8-{[4(phenylazo)phenyl]azo}-7-naphthol-1,3-disulfonic acid disodium salt(CI 27290; Acid Red No. 73), 2′,4′,5′,7′-tetrabromo-3′,6′-dihydroxyspiro{isobenzofuran-1 (3H),9′-[9H]-xanthen}-3-one disodiumsalt (CI 45380; Acid Red No. 87), 2′, 4′, 5′,7′-tetrabromo-4,5,6,7-tetrachloro-3′,6′-dihydroxyspiro{isobenzofuran-1(3H),9′-[9H]-xanthen}-3-one disodiumsalt (CI 45410; Acid Red No. 92), 3′, 6′-dihydroxy-4′,5′-diiodospiro{isobenzofuran-1(3H),9′-(9H)xanthen}-3-one disodium salt(CI 45425; Acid Red No. 95),(2-sulfophenyl)di[4(ethyl-((4sulfophenyl)methyl)amino)phenyl]-carbeniumdisodium salt betaine (CI 42090; Acid Blue No. 9; FD&C Blue No. 1),1,4-bis[(2-sulfo-4-methylphenyl)amino]-9,10-anthraquinone disodium salt(CI 61570; Acid Green No. 25),bis[4-(dimethylamino)phenyl]-(3,7-disulfo-2-hydroxynaphth-1-yl)carbeniuminner salt, monosodium salt (CI 44090; Food Green No. 4; Acid Green No.50), bis[4-(di-ethylamino)phenyl](2,4disulfophenyl)carbenium inner salt,sodium salt (2:1) (CI 42045; Food Blue No. 3; Acid Blue No. 1),bis[4-(diethylamino)phenyl](5-hydroxy-2,4-disulfophenyl)carbenium innersalt, calcium salt (2:1) (CI 42051; Acid Blue No. 3),1-amino-4-(cyclohexylamino)-9,10-anthraquinone-2-sulfonic acid sodiumsalt (CI 62045; Acid Blue No. 62),2-(1,3-dihydro-3-keto-5-sulfo-2H-indol-2-ylidene)-2,3-dihydro-3-keto-1H-indole-5-sulfonicacid disodium salt (CI 73015; Acid Blue No. 74),9-(2-carboxyphenyl)-3-[(2-methylphenyl)amino]-6-[(2-methyl-4-sulfophenyl)amino]xanthyliuminner salt, monosodium salt (CI 45190; Acid Violet No. 9),1-hydroxy-4-[(4-methyl-2-sulfophenyl)amino]-9,10-anthraquinone sodiumsalt (CI 60730; D&C Violet No. 2; Acid Violet No. 43),bis{3-nitro-4-[(4-phenylamino)-3-sulfophenylamino]phenyl} sulfone (CI10410; Acid Brown No. 13),5-amino-4-hydroxy-6-[(4nitrophenyl)azo]-3-(phenylazo)-2,7-naphthalenedisulfonicacid disodium salt (CI 20470; Acid Black No. 1),3-hydroxy-4-[(2-hydroxynaphth-1-yl)azo]-7-nitro-1-naphthalenesulfonicacid chromium complex (3:2) (CI 15711; Acid Black No. 52),3-[(2,4dimethyl-5-sulfophenyl)azo]-4-hydroxy-1-naphthalenesulfonic aciddisodium salt (CI 14700; Food Red No. 1; FD&C Red No. 4),4-(acetylamino)-5-hydroxy-6-[(7-sulfo-4-[(4-sulfophenyl)azo]naphth-1-yl)azo]-1,7-naphthalene-disulfonicacid tetrasodium salt (CI 28440; Food Black No. 1) and3-hydroxy-4(3-methyl-5-keto-1-phenyl-4,5-dihydro-1H-pyrazol-4-ylazo)naphthalene-1-sulfonicacid sodium salt, chromium complex (Acid Red No. 195), alone or incombination with one another

The total amount of direct dyes in the dye carrier composition of theinvention is about 0.01 to 7 weight percent and preferably about 0.2 to4 weight percent.

Other common dyes known to be used for hair coloring and that can becontained in the colorant of the invention are described in, among otherpublications, E. Sagarin, “Cosmetics, Science and Technology”,Interscience Publishers Inc., New York (1957), pages 503 ff, in H.Janistyn, “Handbuch der Kosmetika und Riechstoffe” [Handbook ofCosmetics and Fragrances], vol. 3 (1973), pages 388 ff. and in K.Schrader “Grundlagen und Rezepturen der Kosmetika” [Fundamentals andFormulations of Cosmetics], 2nd edition, (1989), pages 782 to 815, towhich we hereby specifically refer.

Although oxidation colorants are preferred, the dye carrier compositionof the invention can, of course, also be in the form of a nonoxidativecolorant based on the afore-said direct dyes. Furthermore, the dyecarrier composition of the invention can contain antioxidants, forexample ascorbic acid, thioglycolic acid or sodium sulfite, as well ascomplexing agents for heavy metals, for example anethylenediaminetetraacete or nitriloacetic acid, in an amount of up toabout 0.5 weight percent. Perfume oils can be contained in the dyecarrier composition of the invention in an amount of up to about 1weight percent. Naturally, the afore-described dye carrier compositioncan optionally also contain other additives commonly used in haircolorants, for example thickeners such as, for example, the homopolymersof acrylic acid, vegetable gums, derivatives of cellulose and starch,algal polysaccharides, amphiphilic associative thickeners, moreoverpreservatives, antioxidants, for example sodium sulfite, thioglycolicacid and ascorbic acid, complexing agents, solvents such as water, loweraliphatic alcohols, for example aliphatic alcohols with 1 to 4 carbonatoms such as ethanol, propanol and isopropanol, or glycols such asglycerol and 1,2-propylene glycol, wetting agents or emulsifiers fromthe classes of anionic, amphoteric or nonionic surfactants not mentionedin the main claims, moreover softeners, vaseline, silicone oils,paraffin oil, polysorbates and fatty acids as well as hair-care agentssuch as cationic polymers or resins, lanolin derivatives, cholesterol,vitamins, pantothenic acid and betaine. The said constituents are usedin amounts normally employed for such purposes, for example the wettingagents and emulsifiers at a concentration of 0.1 to 30 weight percentand the hair-care agents at a concentration of 0.1 to 5.0 weightpercent.

For nonoxidative colorants based on direct dyes, the pH of the dyecarrier composition of the invention is in the range from about 5 to 10and preferably from 6 to 9, whereas for oxidative colorants based onoxidation dye precursors the pH is in the range from about 6 to 12 andpreferably from 9 to 11. The pH of the ready-to-use oxidation haircolorant (namely the mixture of the dye carrier composition of theinvention and the oxidant) is about 5.5 to 10 and preferably 6 to 9.

Depending on the composition and the desired pH, the pH is preferablyadjusted with ammonia or an organic amine, for example a glucamine,aminomethylpropanol, monoethanolamine or triethanolamine, an inorganicbase, for example sodium hydroxide, potassium hydroxide, sodiumcarbonate or calcium hydroxide, or with an organic or inorganic acid,for example lactic acid, citric acid, acetic acid or phosphoric acid.

The dye carrier composition of the invention is preferably packaged inthe form of an aqueous or aqueous-alcoholic preparation, for example asa thickened solution, emulsion, cream or gel.

For oxidative coloring, the afore-described dye carrier composition ismixed with an oxidant just before use, and an amount of the ready-to-usepreparation sufficient for the coloring, as a rule about 60 to 200grams, is applied to the fibers.

If the dye carrier composition of the invention contains no oxidationdye precursors or contains oxidation dye precursors that are readilyoxidized by atmospheric oxygen, it can be applied to the keratin fibersdirectly without previous mixing with an oxidant.

Suitable oxidants for developing the coloration are mainly hydrogenperoxide or the addition compounds thereof to urea, melamine or sodiumborate in the form of a 1 to 12 percent, preferably 1.5 to 6 percentaqueous solution. The mixing ratio of dye carrier composition to oxidantdepends on the concentration of the oxidant and as a rule is about 5:1to 1:2 and preferably 1:1, the oxidant being contained in theready-to-use preparation preferably in an amount from about 0.5 to 8weight percent and particularly from 1 to 4 weight percent.

The ready-to-use colorant is allowed to act on the keratin fibers (forexample on human hair) at 15 to 50° C. for about 10 to 45 minutes andpreferably for about 15 to 30 minutes after which the fibers are rinsedwith water. Optionally, following this rinsing the fibers are washedwith a shampoo and possibly post-rinsed with a weak organic acid, forexample tartaric acid. The keratin fibers are then dried.

The dye carrier composition of the invention has a uniform consistencyand produces a highly cosmetic, nacreous luster effect. A colorantprepared with the dye carrier composition of the invention meets therequirements in terms of adhesion properties, application performanceand viscosity adjustment in outstanding manner and through the nacreouscharacter provides a highly cosmetic appearance. In addition, comparedto the known colorants, it gives a clearly improved hair-care effectafter rinsing.

Another object of the present application is the use of a combination of

-   (a) at least one fatty alcohol with 14 to 20 carbon atoms,-   (b) at least one alkanolamide,-   (c) at least one fatty alcohol alkoxylate or fatty acid alkoxylate    and-   (d) at least one anionic surfactant,    the weight ratio of fatty alcohol (a) to alkanolamide (b) being    equal to 0.5:2 to 2:0.5, for producing a nacreous luster effect in    dye carrier compositions and colorants for keratin fibers,    particularly human hair.

Particularly preferred is the use of a combination of

-   (a) 6.1 to 20 weight percent, particularly 7 to 12 weight percent,    of at least one fatty alcohol with 14 to 20 carbon atoms,-   (b) 6.1 to 20 weight percent and particularly 7 to 12 weight percent    of at least one alkanolamide,-   (c) 0.1 to 15 weight percent and particularly 7 to 12 weight percent    of at least one fatty alcohol alkoxylate or fatty acid alkoxylate,    and-   (d) 0.1 to 15 weight percent and particularly 7 to 12 weight    percent, of at least one anionic surfactant, the weight ratio of    fatty alcohol (a) to alkanolamide (b) being equal to 0.5:2 to 2:0.5    and particularly 0.8:1.2 to 1.2:0.8.

The following examples will explain the subject matter of the inventionin greater detail without limiting it to the examples.

EXAMPLES Example 1 Oxidation Hair Colorant, Creamy

6.0000 g of stearyl alcohol 5.0000 g of cetyl alcohol 8.0000 g of cocofatty acid monoethanolamide (Cocamide MEA) 4.0000 g ofpolyoxyethylene(10) stearyl ether (Steareth-10) 8.0000 g of sodiumlauryl alcohol diethylene glycol ether sulfate, 28% aqueous solution1.3620 g of 4-aminophenol 0.5000 g of 1-naphthol 0.0136 g of resorcinol0.0034 g of 2-amino-6-chloro-4-nitrophenol 12.0000 g of ammonia, 25%aqueous solution 1.0000 g of disodium ethylenediaminetetraacetate 1.0000g of ascorbic acid to 100.0000 g water

Just before use, 50 g of the foregoing dye carrier composition with anacreous luster was mixed with 50 g of a 6% aqueous hydrogen peroxidesolution. This gave a homogeneous, cosmetically attractive colorantpreparation with a nacreous luster. The mixture thus obtained was thenapplied to natural blond hair. After an exposure time of 30 minutes at40° C., the hair was rinsed with water and dried. The hair had a brightcopper-red color.

Example 2 Oxidation Hair Colorant for Color-Brightening Component (A):Creamy Dye Carrier Composition

12.00 g of cetylstearyl alcohol 8.00 g of coco fatty acidmonoethanolamide (Cocamide MEA) 6.00 g of polyoxyethylene(25)cetylstearyl ether (Ceteareth-25) 1.00 g of oleic acid 4.00 g of sodiumlauryl alcohol diethylene glycol ether sulfate, 70% aqueous solution0.50 g of p-phenylenediamine 0.07 g of resorcinol 1.00 g of disodiumethylenediaminetetraacetate 8.00 g of ammonia, 25% aqueous solution 8.00g of ethanol to 100.00 g water

Component B: Hydrogen Peroxide Emulsion

10.0 g of cetylstearyl alcohol 1.5 g of cholesterol 4.0 g of sodiumlauryl alcohol diethylene glycol ether sulfate, 28% aqueous solution35.0 g of hydrogen peroxide, 35% aqueous solution 0.3 g of perfume to100.0 g water

Just before use, 40 g of the liquid dye carrier composition (A) with anacreous luster was mixed with 80 g of the hydrogen peroxide emulsion(B) which corresponded to an (A):(B) mixing ratio of 1:2, and 120 g ofthis mixture was applied to gray human hair. After an exposure time of20 minutes at room temperature, the hair was rinsed with water anddried. The hair treated in this manner had a uniform light-brown colorfrom the roots to the tips. The ready-to-use agent had a cosmeticnacreous luster, was easy to apply to the hair and did not run off thehair.

Example 3 Oxidation Hair Colorant, Creamy

4.00 g of cetylstearyl alcohol 5.00 g of stearyl alcohol 12.00 g of cocofatty acid monoethanolamide (Cocamide MEA) 2.00 g of polyoxyethylene(20)stearyl ether (Steareth-20) 8.00 g of sodium lauryl alcohol diethyleneglycol ether sulfate, 28% aqueous solution 8.00 g of monoethanolamine1.30 g of 1-methyl-2,5-diaminobenzene 1.50 g of diallyldiammoniumchloride/hydroxyethylcellulose copolymer (Polyquaternium-4) 0.65 g ofresorcinol 0.50 g of keratin hydrolyzate 0.50 g of silk proteinhydrolyzate 0.52 g of 2-amino-6-chloro-4-nitrophenol 1.00 g of disodiumethylenediaminetetraacetate 0.30 g of ascorbic acid to 100.00 g water

Just before use, 50 g of the foregoing dye carrier composition with anacreous luster was mixed with 50 g of a 12% aqueous hydrogen peroxidesolution. The resulting mixture was then applied to natural blond hair.After an exposure time of 30 minutes at 40° C., the hair was rinsed withwater and dried. This gave a uniform, strong brown shade.

Example 4 Nonoxidative Hair Colorant

6.000 g of stearyl alcohol 4.000 g of myristyl alcohol 8.000 g of cocofatty acid monoethanolamide (Cocamide MEA) 2.000 g ofpolyoxyethylene(20) stearyl ether (Steareth-20) 2.000 g of sodium laurylsulfate 2.000 g of isopropyl alcohol 0.160 g of{{4-{ethyl[(2-hydroxyethyl)amino]-2- nitrophenyl}amino}}ethanolhydrochloride (HC Blue No. 12) 0.170 g of3-{[2-nitro-4-(trifluoromethyl)phenyl]amino}-1,2- propanediol (HC YellowNo. 6) 0.012 g of 1-N-hydroxyethylamino-4-methyl-2-nitrobenzene 0.035 gof HC RED NO. 10 and HC RED NO. 11 (1:1) to 100.000 g water

The creamy dye carrier composition with a nacreous luster was appliedwith gloves to washed and towel-dried, natural blond hair. After anexposure time of 20 to 25 minutes, excess dye was washed out with waterand a shampoo. This gave a beautiful, lustrous medium-blond shade.

Example 5 Nonoxidative Hair Colorant

3.1 g of cetylstearyl alcohol 3.1 g of stearyl alcohol 5.0 g of cocofatty acid diethanolamide (Cocamide DEA) 2.0 g of polyoxyethylene(30)oleyl ether (Oleth-30) 0.5 g of sodium lauryl sulfate 7.0 g of ethanol0.1 g of 1-N-hydroxyethylamino-4-methyl-2-nitrobenzene 0.5 g of HC REDNO. 10 and HC RED NO. 11 (1:1) 0.2 g of 2-amino-6-chloro-4-nitrophenolto 100.0 g water

The creamy dye carrier composition with a nacreous luster was appliedwith gloves to washed and towel-dried, natural blond hair. After anexposure time of 25 to 30 minutes, excess dye was washed out with waterand a shampoo. This gave a lustrous trendy red shade.

Unless otherwise indicated, all percentages given in the presentapplication are by weight.

1. A dye carrier composition with a nacreous luster, said dye carriercomposition containing oxidative dyes and/or nonoxidative dyes, and acombination of: (a) from 6.1 to 20 weight percent of at least one fattyalcohol with 14 to 20 carbon atoms, (b) from 6.1 to 20 weight percent ofat least one alkanolamide, (c) from 0.1 to 15 weight percent of at leastone fatty alcohol alkoxylate or fatty acid alkoxylate, and (d) from 0.1to 15 weight percent of at least one anionic surfactant; wherein aweight ratio of said fatty alcohol to said alkanolamide is from 0.5:2 to2:0.5.
 2. The dye carrier composition as defined in claim 1, whereinsaid weight ratio of said fatty alcohol to said alkanolamide is from0.8:1.2 to 1.2:0.8.
 3. The dye carrier composition as defined in claim1, wherein a weight ratio of said alkoxylate to said anionic surfactantis from 0.5:2 to 2:0.5.
 4. The dye carrier composition as defined inclaim 1, wherein said fatty alcohol is selected from the groupconsisting of cetyl alcohol, stearyl alcohol, myristyl alcohol, isooctylalcohol, isotridecyl alcohol and mixtures thereof.
 5. The dye carriercomposition as defined in claim 1, wherein said at least onealkanolamide is selected from the group consisting of N-acyl derivativesof monoethanolamine and N-acyl derivatives of diethanolamine.
 6. The dyecarrier composition as defined in claim 1, wherein said alkoxylateconsists of at least one ethoxylated fatty alcohol of formula (I):CH₃(CH₂)—X—O—(R_(y))—H  (I), wherein R=—(CH2—CH2—O)—or —(CH3—CH—CH2—O)—,and X represents C₈-C₁₈and y denotes 2 to
 300. 7. The dye carriercomposition as defined in claim 1, wherein said at least one anionicsurfactant is selected from the group consisting of carboxylic acidsalts, carboxylic acid esters, alkyl ether sulfates, alkyl sulfates,fatty alcohol ether sulfates, sulfonic acids, salts of sulfonic acids,phosphate esters, phosphate salts, acylamino acids and salts ofacylamino acids.
 8. The dye carrier composition as defined in claims 1,containing a total amount of from 7 to 12 weight percent of each of saidfatty alcohol, said alkanolamide, said alkoxylate, and said anionicsurfactant.
 9. The dye carrier composition as defined in claim 1, andfree of monomeric quaternary ammonium compounds and free of cationicemulsifiers and surfactants.
 10. The dye carrier composition as definedin claims 1, containing from 0.1 to 10 weight percent of ethylene glycoldistearate.
 11. An agent for oxidative coloring of hair obtained bymixing a dye carrier composition with an oxidant; wherein said dyecarrier composition contains oxidative dyes and/or nonoxidative dyes,and a combination of: (a) from 6.1 to 20 weight percent of at least onefatty alcohol with 14 to 20 carbon atoms, (b) from 6.1 to 20 weightpercent of at least one alkanolamide, (c) from 0.1 to 15 weight percentof at least one fatty alcohol alkoxylate or fatty acid alkoxylate, and(d) from 0.1 to 15 weight percent of at least one anionic surfactant;wherein a weight ratio of said fatty alcohol to said alkanolamide isfrom 0.5:2 to 2:0.5.
 12. The agent as defined in claim 11, wherein saidoxidant is hydrogen peroxide.
 13. A method of making a dye carriercomposition or a colorant for keratin fibers with a nacreous luster,said method comprising the step of including in said dye carriercomposition a combination of: (a) from 6.1 to 20 weight percent of atleast one fatty alcohol with 14 to 20 carbon atoms, (b) from 6.1 to 20weight percent of at least one alkanolamide, (c) from 0.1 to 15 weightpercent of at least one fatty alcohol alkoxylate or fatty acidalkoxylate, and (d) from 0.1 to 15 weight percent of at least oneanionic surfactant; wherein a weight ratio of said at least one fattyalcohol to said at least one alkanolamide (b) is from 0.5:2 to 2:0.5.